100 Important MCQs (Set-1 Basic Level) on Heat and Thermodynamics, Physics (Unit-Wise MCQs Practice):


This post contains 100 carefully selected multiple-choice questions (MCQs) (Set-1 Basic Level) on the unit of Physics: Heat and Thermodynamics, designed according to all board exams syllabus. These MCQs include a well-balanced mix of conceptual and numerical problems, making them exam-ready, revision-friendly, and high-scoring for students.

Whether you are preparing for annual board examinations, chapter tests, or competitive entry tests, this comprehensive MCQ collection thoroughly covers all the fundamental principles of thermodynamics, helping students build strong conceptual understanding and problem-solving skills.

This unit-wise 100 MCQ (set- 1 Basic  level) on Heat and Thermodynamics includes questions from:

  • Concept of thermodynamic systems and surroundings
  • Types of systems: open, closed, and isolated systems
  • State variables and thermodynamic equilibrium
  • Zeroth Law of Thermodynamics and concept of temperature
  • Heat, work, and internal energy
  • First Law of Thermodynamics and its mathematical expression
  • Applications of the First Law in isothermal, isobaric, isochoric, and adiabatic processes
  • Thermodynamic processes and P–V diagrams
  • Specific heat capacities and calorimetry
  • Heat engines and their working principles
  • Efficiency of heat engines and Carnot engine
  • Second Law of Thermodynamics and its statements
  • Reversible and irreversible processes
  • Entropy and its physical significance
  • Practical applications of thermodynamics in daily life and technology

    Each MCQ is provided with the correct answer and a clear, concise explanation, helping students:

    • Strengthen their conceptual understanding of heat and energy transfer
    • Avoid common mistakes in numerical and conceptual questions
    • Improve problem-solving skills in thermodynamics
    • Achieve maximum marks in the MCQs section of exams

      These 100 Thermodynamics MCQ collection is an essential resource for the students who want to master thermodynamics concepts and score high in physics examinations.



      Topic: Heat Transfer & Temperature

      MCQs No.1

      Thermal energy flows naturally from:

      a) Lower temperature to higher temperature
      b) Higher temperature to lower temperature
      c) Equal temperatures
      d) Any direction

      Correct Answer is option b. Higher temperature to lower temperature

      Explanation: Heat flows from hot to cold until equilibrium is achieved.


      Topic: Thermal Equilibrium (Zeroth Law)

      2. Two bodies are in thermal equilibrium if they have:
      a) Equal pressure
      b) Equal temperature
      c) Equal volume
      d) Equal mass

      Correct Answer is option b. Equal temperature

      Explanation: No net heat flow occurs when temperatures are equal.


      Topic: Heat and Work as Energy Transfer

      3. Heat and work are:
      a) Forms of matter
      b) Forms of energy transfer
      c) State variables
      d) Mechanical quantities only

      Correct Answer is option b. Forms of energy transfer

      Explanation: Energy can cross system boundaries as heat or work.


      Topic: Definition of Thermodynamics

      4. Thermodynamics is the study of:
      a) Motion of particles
      b) Heat, work, and energy
      c) Electricity
      d) Nuclear reactions

      Correct Answer is option b. Heat, work, and energy

      Explanation: Thermodynamics deals with energy transformations.


      Topic: Internal Energy Concept

      5. Internal energy of a gas is mainly due to:
      a) Macroscopic motion
      b) Gravitational energy
      c) Molecular kinetic and potential energies
      d) External work

      Correct Answer is option c. Molecular kinetic and potential energies

      Explanation: Internal energy arises from random molecular motion and interactions.


      Topic: Internal Energy vs Temperature

      6. Increase in temperature of a body results in:
      a) Decrease in internal energy
      b) No change in internal energy
      c) Increase in internal energy
      d) Zero internal energy

      Correct Answer is option c. Increase in internal energy

      Explanation: Higher temperature means higher molecular kinetic energy.


      Topic: Mechanical Equivalent of Heat

      7. Mechanical equivalent of heat relates:
      a) Mass and energy
      b) Work and heat
      c) Pressure and volume
      d) Temperature and entropy

      Correct Answer is option b. Work and heat

      Explanation: It shows how mechanical work converts into heat.


      Topic: Work Done by Gas (Isobaric Process)

      8. Work done by gas at constant pressure is:
      a) Zero
      b) PΔV
      c) ΔU
      d) Q − ΔU

      Correct Answer is option b. PΔV

      Explanation: For isobaric process, work = pressure × change in volume.


      Topic: First Law of Thermodynamics

      9. First law of thermodynamics is:
      a) ΔU = W − Q
      b) ΔU = Q − W
      c) ΔU = 0
      d) Q = W

      Correct Answer is option b. ΔU = Q − W

      Explanation: Change in internal energy equals heat added minus work done.


      Topic: Conservation of Energy

      10. First law of thermodynamics expresses:
      a) Entropy law
      b) Energy conservation
      c) Temperature law
      d) Pressure law

      Correct Answer is option b. Energy conservation

      Explanation: Energy cannot be created or destroyed.


      Topic: Numerical (First Law)

      11. A gas absorbs 500 J heat and does 200 J work. ΔU = ?
      a) 300 J
      b) 700 J
      c) -300 J
      d) 200 J

      Correct Answer is option a. 300 J

      Explanation: ΔU = 500 − 200 = 300 J.


      Topic: Specific Heat

      12. Specific heat capacity is heat required to raise temperature of:
      a) 1 kg by 1 K
      b) 1 g by 1 K
      c) 1 mole by 1 K
      d) Any mass by 1 K

      Correct Answer is option a. 1 kg by 1 K

      Explanation: It is defined per unit mass.


      Topic: Molar Specific Heat

      13. Molar specific heat is heat required to raise temperature of:
      a) 1 kg
      b) 1 g
      c) 1 mole
      d) 1 liter

      Correct Answer is option c. 1 mole

      Explanation: It is defined per mole of substance.


      Topic: Cp and Cv Relation

      14. For ideal gas, Cp − Cv equals:
      a) 0
      b) R
      c) 2R
      d) 1/R

      Correct Answer is option b. R

      Explanation: This is Mayer’s relation.


      Topic: First Law Application

      15. For constant volume process, heat added equals:
      a) Work done
      b) ΔU
      c) PΔV
      d) Zero

      Correct Answer is option b. ΔU

      Explanation: No work is done at constant volume.


      Topic: Heat Engine Principle

      16. A heat engine converts:
      a) Work into heat
      b) Heat into work
      c) Heat into temperature
      d) Work into entropy

      Correct Answer is option b. Heat into work

      Explanation: Heat engines convert thermal energy into mechanical work.


      Topic: Reversible Process

      17. A reversible process is one that:
      a) Happens suddenly
      b) Can be reversed without leaving change
      c) Always irreversible
      d) Occurs with friction

      Correct Answer is option b. Can be reversed without leaving change

      Explanation: Reversible processes occur infinitely slowly without losses.


      Topic: Irreversible Process

      18. Free expansion of gas is an example of:
      a) Reversible process
      b) Isothermal process
      c) Irreversible process
      d) Adiabatic process

      Correct Answer is option c. Irreversible process

      Explanation: Free expansion cannot be reversed without external work.


      Topic: Second Law of Thermodynamics

      19. Second law states that entropy of an isolated system:
      a) Decreases
      b) Remains constant
      c) Increases
      d) Becomes zero

      Correct Answer is option c. Increases

      Explanation: Natural processes increase disorder.


      Topic: Carnot Engine

      20. Carnot engine is:
      a) Real engine
      b) Ideal reversible engine
      c) Diesel engine
      d) Refrigerator

      Correct Answer is option b. Ideal reversible engine

      Explanation: Carnot engine represents maximum theoretical efficiency.


      Topic: Carnot Efficiency

      21. Carnot efficiency depends on:
      a) Nature of gas
      b) Working substance
      c) Temperatures of reservoirs
      d) Pressure

      Correct Answer is option c. Temperatures of reservoirs

      Explanation: η = 1 − Tc/Th.


      Topic: Refrigerator Concept

      22. A refrigerator is a heat engine operating:
      a) Normally
      b) With zero work
      c) In reverse direction
      d) At constant temperature

      Correct Answer is option c. In reverse direction

      Explanation: It removes heat from cold body using work.


      Topic: Coefficient of Performance (COP)

      23. COP of refrigerator is:
      a) W/Qc
      b) Qc/W
      c) Qh/W
      d) W/Qh

      Correct Answer is option b. Qc/W

      Explanation: It measures cooling efficiency.


      Topic: Entropy and Heat

      24. Entropy increases when:
      a) Heat is removed
      b) Heat is added
      c) Temperature decreases
      d) Volume decreases

      Correct Answer is option b. Heat is added

      Explanation: Adding heat increases disorder.


      Topic: Disorder and Entropy

      25. Increase in entropy means:
      a) More order
      b) Less disorder
      c) Energy degradation
      d) Energy creation

      Correct Answer is option c. Energy degradation

      Explanation: Energy becomes less available for useful work.


      Topic: Internal Energy as State Function

      26. Internal energy of a system is a:
      a) Path function
      b) State function
      c) External variable
      d) Vector quantity

      Correct Answer is option b. State function

      Explanation: Internal energy depends only on the state, not the path.


      Topic: Internal Energy (Ideal Gas)

      27. For an ideal gas, internal energy depends on:
      a) Pressure
      b) Volume
      c) Temperature only
      d) Density

      Correct Answer is option c. Temperature only

      Explanation: For ideal gas, U is a function of temperature.


      Topic: Work Done (General Concept)

      28. Work done by a gas during expansion is equal to:
      a) ΔU
      b) PΔV
      c) Q
      d) mgh

      Correct Answer is option b. PΔV

      Explanation: Work is done when volume changes under pressure.


      Topic: Isothermal Process

      29. In an isothermal process, the temperature of gas:
      a) Increases
      b) Decreases
      c) Remains constant
      d) Becomes zero

      Correct Answer is option c. Remains constant

      Explanation: Isothermal means constant temperature.


      Topic: Isochoric Process

      30. In an isochoric process, work done is:
      a) Maximum
      b) Minimum
      c) Zero
      d) Equal to Q

      Correct Answer is option c. Zero

      Explanation: Volume is constant, so ΔV = 0, hence W = 0.


      Topic: Adiabatic Process

      31. In an adiabatic process, heat exchange is:
      a) Maximum
      b) Minimum
      c) Zero
      d) Infinite

      Correct Answer is option c. Zero

      Explanation: Adiabatic means no heat transfer (Q = 0).


      Topic: Temperature Change in Adiabatic Expansion

      32. During adiabatic expansion, gas temperature:
      a) Increases
      b) Decreases
      c) Remains constant
      d) Becomes zero

      Correct Answer is option b. Decreases

      Explanation: Gas does work, reducing internal energy and temperature.


      Topic: Specific Heat (Cp and Cv)

      33. Cp is greater than Cv because:
      a) Gas expands at constant pressure
      b) Gas compresses
      c) Temperature decreases
      d) Volume remains constant

      Correct Answer is option a. Gas expands at constant pressure

      Explanation: Extra heat is required to do expansion work.


      Topic: Mayer’s Relation

      34. The relation Cp − Cv = R is known as:
      a) Boyle’s law
      b) Charles’ law
      c) Mayer’s relation
      d) Carnot law

      Correct Answer is option c. Mayer’s relation

      Explanation: It relates molar specific heats of ideal gases.


      Topic: Degrees of Freedom

      35. For a monoatomic gas, Cv equals:
      a) R
      b) 3/2 R
      c) 5/2 R
      d) 7/2 R

      Correct Answer is option b. 3/2 R

      Explanation: Monoatomic gases have 3 translational degrees of freedom.


      Topic: Numerical (Internal Energy)

      36. One mole of monoatomic gas is heated by 10 K at constant volume. ΔU = ? (R = 8.314 J/mol·K)
      a) 124.7 J
      b) 83.14 J
      c) 166.3 J
      d) 41.57 J

      Correct Answer is option a. 124.7 J

      Explanation: ΔU = nCvΔT = 1 × (3/2 R) × 10.


      Topic: Heat Engine Principle

      37. A heat engine works between:
      a) One reservoir
      b) Two reservoirs at same temperature
      c) Two reservoirs at different temperatures
      d) Three reservoirs

      Correct Answer is option c. Two reservoirs at different temperatures

      Explanation: Heat must flow from hot to cold reservoir.


      Topic: Heat Engine Efficiency

      38. Efficiency of heat engine is defined as:
      a) Qh/W
      b) W/Qh
      c) Qc/W
      d) Qh/Qc

      Correct Answer is option b. W/Qh

      Explanation: Efficiency = useful work output / heat absorbed.


      Topic: Carnot Efficiency Numerical

      39. If Th = 600 K and Tc = 300 K, Carnot efficiency is:
      a) 25%
      b) 33%
      c) 50%
      d) 75%

      Correct Answer is option c. 50%

      Explanation: η = 1 − Tc/Th = 1 − 300/600 = 0.5.


      Topic: Reversible Process

      40. A reversible process must occur:
      a) Rapidly
      b) With friction
      c) Infinitely slowly
      d) With heat loss

      Correct Answer is option c. Infinitely slowly

      Explanation: It must remain in equilibrium at all times.


      Topic: Irreversible Process

      41. Which of the following is irreversible?
      a) Slow compression
      b) Slow expansion
      c) Free expansion
      d) Quasi-static process

      Correct Answer is option c. Free expansion

      Explanation: Free expansion cannot be reversed without external changes.


      Topic: Refrigerator Concept

      42. Refrigerator transfers heat from:
      a) Hot to cold body
      b) Cold to hot body using work
      c) Hot to hot body
      d) Cold to cold body

      Correct Answer is option b. Cold to hot body using work

      Explanation: Work is required to pump heat against natural flow.


      Topic: Coefficient of Performance (COP)

      43. COP of refrigerator is maximum when:
      a) Tc is high and Th is low
      b) Tc is low and Th is high
      c) Tc and Th are equal
      d) Work is zero

      Correct Answer is option a. Tc is high and Th is low

      Explanation: Smaller temperature difference increases COP.


      Topic: Entropy Change

      44. Entropy change for heat addition at temperature T is:
      a) ΔS = QT
      b) ΔS = Q/T
      c) ΔS = T/Q
      d) ΔS = Q×T

      Correct Answer is option b. ΔS = Q/T

      Explanation: Entropy change is heat divided by absolute temperature.


      Topic: Entropy and Disorder

      45. Entropy increases when:
      a) Gas is compressed
      b) Gas is cooled
      c) Gas expands freely
      d) Heat is removed

      Correct Answer is option c. Gas expands freely

      Explanation: Free expansion increases randomness.


      Topic: Energy Degradation

      46. Energy degradation means energy:
      a) Is destroyed
      b) Becomes less useful
      c) Becomes heat always
      d) Becomes zero

      Correct Answer is option b. Becomes less useful

      Explanation: High-quality energy converts to low-quality heat.


      Topic: Natural Processes

      47. In all natural processes, entropy:
      a) Decreases
      b) Remains constant
      c) Increases
      d) Becomes zero

      Correct Answer is option c. Increases

      Explanation: Natural processes are irreversible and increase disorder.


      Topic: Order of Systems

      48. With passage of time, systems tend to become:
      a) More orderly
      b) Less orderly
      c) Perfectly ordered
      d) Constantly ordered

      Correct Answer is option b. Less orderly

      Explanation: Entropy increases with time.


      Topic: Numerical (First Law)

      49. A system absorbs 800 J heat and does 300 J work. ΔU = ?
      a) 500 J
      b) 1100 J
      c) 300 J
      d) 800 J

      Correct Answer is option a. 500 J

      Explanation: ΔU = Q − W = 800 − 300 = 500 J.


      Topic: Numerical (Work Calculation)

      50. A gas expands from 1 m³ to 4 m³ at pressure 2×10⁵ Pa. Work done is:
      a) 2×10⁵ J
      b) 4×10⁵ J
      c) 6×10⁵ J
      d) 8×10⁵ J

      Correct Answer is option c. 6×10⁵ J

      Explanation: W = PΔV = 2×10⁵ × (4 − 1) = 6×10⁵ J.



      opic: Specific Heat at Constant Pressure

      51. Specific heat at constant pressure is denoted by:
      a) Cv
      b) Cp
      c) R
      d) U

      Correct Answer is option b. Cp

      Explanation: Cp is molar specific heat at constant pressure.


      Topic: Cp and Cv Relation

      52. For an ideal gas, Cp/Cv is called:
      a) R
      b) γ (gamma)
      c) η
      d) k

      Correct Answer is option b. γ (gamma)

      Explanation: γ = Cp/Cv, also called adiabatic index.


      Topic: Adiabatic Index

      53. For a monoatomic gas, γ is approximately:
      a) 1.33
      b) 1.4
      c) 1.67
      d) 2.0

      Correct Answer is option c. 1.67

      Explanation: γ = 5/3 for monoatomic gases.


      Topic: Internal Energy Numerical

      54. Two moles of diatomic gas heated by 20 K at constant volume. Cv = 5/2 R. ΔU = ?
      a) 415.7 J
      b) 831.4 J
      c) 1662.8 J
      d) 2078.5 J

      Correct Answer is option b. 831.4 J

      Explanation: ΔU = nCvΔT = 2 × (5/2 × 8.314) × 20.


      Topic: Work Done (Isothermal)

      55. In isothermal expansion of ideal gas, internal energy change is:
      a) Positive
      b) Negative
      c) Zero
      d) Infinite

      Correct Answer is option c. Zero

      Explanation: For ideal gas, U depends only on temperature, which is constant.


      Topic: First Law Application

      56. If ΔU = 0 and Q = 200 J, work done is:
      a) 200 J
      b) 0 J
      c) -200 J
      d) 400 J

      Correct Answer is option a. 200 J

      Explanation: From ΔU = Q − W, W = Q.


      Topic: Heat Engine Efficiency

      57. A heat engine absorbs 800 J and rejects 500 J. Efficiency is:
      a) 12.5%
      b) 37.5%
      c) 50%
      d) 62.5%

      Correct Answer is option b. 37.5%

      Explanation: W = 800 − 500 = 300 J; η = 300/800.


      Topic: Carnot Engine Theory

      58. Carnot cycle consists of:
      a) Two isobaric and two isochoric processes
      b) Two isothermal and two adiabatic processes
      c) Four isothermal processes
      d) Four adiabatic processes

      Correct Answer is option b. Two isothermal and two adiabatic processes

      Explanation: Carnot cycle is ideal reversible cycle.


      Topic: Carnot Efficiency Concept

      59. If Tc approaches Th, Carnot efficiency becomes:
      a) Maximum
      b) Zero
      c) Infinite
      d) Constant

      Correct Answer is option b. Zero

      Explanation: η = 1 − Tc/Th → 0 when Tc ≈ Th.


      Topic: Refrigerator COP Numerical

      60. A refrigerator removes 400 J from cold reservoir using 100 J work. COP = ?
      a) 2
      b) 3
      c) 4
      d) 5

      Correct Answer is option c. 4

      Explanation: COP = Qc/W = 400/100 = 4.


      Topic: Second Law (Kelvin-Planck Statement)

      61. Kelvin-Planck statement says it is impossible to:
      a) Convert work into heat
      b) Convert heat completely into work
      c) Increase entropy
      d) Transfer heat from cold to hot

      Correct Answer is option b. Convert heat completely into work

      Explanation: No heat engine can be 100% efficient.


      Topic: Clausius Statement

      62. Clausius statement says it is impossible for heat to flow:
      a) From hot to cold
      b) From cold to hot without work
      c) Between equal temperatures
      d) In isolated system

      Correct Answer is option b. From cold to hot without work

      Explanation: Refrigerator requires work to transfer heat backward.


      Topic: Entropy Calculation

      63. If 200 J heat is added at 400 K, entropy change is:
      a) 0.25 J/K
      b) 0.5 J/K
      c) 1 J/K
      d) 2 J/K

      Correct Answer is option b. 0.5 J/K

      Explanation: ΔS = Q/T = 200/400.


      Topic: Entropy and Temperature

      64. For same heat added, entropy change is greater at:
      a) High temperature
      b) Low temperature
      c) Constant temperature
      d) Zero temperature

      Correct Answer is option b. Low temperature

      Explanation: ΔS = Q/T, so smaller T gives larger ΔS.


      Topic: Energy Degradation Concept

      65. High-grade energy refers to:
      a) Random heat
      b) Low temperature energy
      c) Organized energy like work
      d) Entropy

      Correct Answer is option c. Organized energy like work

      Explanation: Work is high-quality energy.


      Topic: Natural Processes

      66. Which process is spontaneous?
      a) Decrease in entropy
      b) Constant entropy
      c) Increase in entropy
      d) Zero entropy

      Correct Answer is option c. Increase in entropy

      Explanation: Spontaneous processes increase entropy.


      Topic: Work Done Sign Convention

      67. When gas does work on surroundings, W is taken as:
      a) Positive
      b) Negative
      c) Zero
      d) Infinite

      Correct Answer is option a. Positive

      Explanation: By physics convention, work done by system is positive.


      Topic: Work Done on System

      68. When surroundings do work on gas, W is:
      a) Positive
      b) Negative
      c) Zero
      d) Maximum

      Correct Answer is option b. Negative

      Explanation: Work done on system is negative.


      Topic: Internal Energy Change

      69. If Q = 300 J and W = 500 J, ΔU = ?
      a) 200 J
      b) -200 J
      c) 800 J
      d) 0 J

      Correct Answer is option b. -200 J

      Explanation: ΔU = Q − W = 300 − 500 = −200 J.


      Topic: System and Surroundings

      70. The universe in thermodynamics consists of:
      a) System only
      b) Surroundings only
      c) System + surroundings
      d) Heat only

      Correct Answer is option c. System + surroundings

      Explanation: Universe includes everything.


      Topic: Closed System

      71. A closed system can exchange:
      a) Mass only
      b) Energy only
      c) Both mass and energy
      d) Neither mass nor energy

      Correct Answer is option b. Energy only

      Explanation: Mass is fixed but energy exchange is allowed.


      Topic: Isolated System

      72. An isolated system exchanges:
      a) Energy only
      b) Mass only
      c) Both mass and energy
      d) Neither mass nor energy

      Correct Answer is option d. Neither mass nor energy

      Explanation: Isolated system is completely sealed.


      Topic: Open System

      73. An open system can exchange:
      a) Mass only
      b) Energy only
      c) Both mass and energy
      d) Neither

      Correct Answer is option c. Both mass and energy

      Explanation: Open system interacts freely with surroundings.


      Topic: Zeroth Law Application

      74. If A is in thermal equilibrium with B and B with C, then A is in equilibrium with C. This is:
      a) First law
      b) Second law
      c) Zeroth law
      d) Boyle’s law

      Correct Answer is option c. Zeroth law

      Explanation: It defines temperature concept.


      Topic: Temperature and Internal Energy

      75. Doubling absolute temperature of ideal gas (constant volume) will:
      a) Double internal energy
      b) Halve internal energy
      c) Make U zero
      d) Not affect U

      Correct Answer is option a. Double internal energy

      Explanation: U ∝ T for ideal gas.


      Topic: Work Calculation Numerical

      76. A gas expands from 3 m³ to 7 m³ at pressure 5×10⁵ Pa. Work done = ?
      a) 2×10⁶ J
      b) 4×10⁶ J
      c) 5×10⁶ J
      d) 1×10⁶ J

      Correct Answer is option b. 4×10⁶ J

      Explanation: W = PΔV = 5×10⁵ × 4.


      Topic: Heat Engine Concept

      77. Heat engine rejects heat to:
      a) Hot reservoir
      b) Cold reservoir
      c) System
      d) Surroundings only

      Correct Answer is option b. Cold reservoir

      Explanation: Waste heat must be rejected to cold sink.


      Topic: Maximum Efficiency

      78. Maximum efficiency of any engine is less than 100% because of:
      a) First law
      b) Second law
      c) Boyle’s law
      d) Charles’ law

      Correct Answer is option b. Second law

      Explanation: Entropy must increase, so some heat is wasted.


      Topic: Entropy and Order

      79. A perfectly ordered crystal at absolute zero has entropy:
      a) Maximum
      b) Infinite
      c) Zero
      d) Negative

      Correct Answer is option c. Zero

      Explanation: Third law states entropy is zero at 0 K.


      Topic: Energy Transformation

      80. Conversion of work into heat is:
      a) Impossible
      b) Possible and complete
      c) Against second law
      d) Reversible only

      Correct Answer is option b. Possible and complete

      Explanation: Work can be fully converted into heat.


      Topic: Irreversibility

      81. Which increases entropy most?
      a) Reversible expansion
      b) Slow compression
      c) Free expansion
      d) Isothermal compression

      Correct Answer is option c. Free expansion

      Explanation: Free expansion is highly irreversible.


      Topic: Refrigerator Efficiency

      82. COP of refrigerator becomes zero when:
      a) Tc = Th
      b) Tc < Th
      c) Th > Tc
      d) Work is maximum

      Correct Answer is option a. Tc = Th

      Explanation: No heat can be removed if both reservoirs are same temperature.


      Topic: Entropy Sign

      83. When heat is removed from a system, entropy change is:
      a) Positive
      b) Negative
      c) Zero
      d) Infinite

      Correct Answer is option b. Negative

      Explanation: Removing heat reduces disorder.


      Topic: Energy Degradation

      84. In all natural processes, high-grade energy changes into:
      a) Work
      b) Mechanical energy
      c) Low-grade heat
      d) Nuclear energy

      Correct Answer is option c. Low-grade heat

      Explanation: Energy becomes less useful.


      Topic: Internal Energy Numerical

      85. One mole of monoatomic gas heated 30 K at constant volume. ΔU = ?
      a) 124.7 J
      b) 249.4 J
      c) 374.1 J
      d) 498.8 J

      Correct Answer is option c. 374.1 J

      Explanation: ΔU = 1 × (3/2 × 8.314) × 30.


      Topic: Work and Heat Transfer

      86. Heat transfer occurs due to:
      a) Pressure difference
      b) Volume difference
      c) Temperature difference
      d) Density difference

      Correct Answer is option c. Temperature difference

      Explanation: Heat flows due to temperature gradient.


      Topic: State Variables

      87. Which is NOT a state variable?
      a) Pressure
      b) Volume
      c) Temperature
      d) Work

      Correct Answer is option d. Work

      Explanation: Work depends on path.


      Topic: Entropy and Disorder

      88. Which system has highest entropy?
      a) Solid
      b) Liquid
      c) Gas
      d) Crystal at 0 K

      Correct Answer is option c. Gas

      Explanation: Gas molecules are most disordered.


      Topic: Heat Engine Output

      89. Work done by heat engine equals:
      a) Qh + Qc
      b) Qh − Qc
      c) Qc − Qh
      d) Qh × Qc

      Correct Answer is option b. Qh − Qc

      Explanation: Work is difference between absorbed and rejected heat.


      Topic: Refrigerator Work

      90. Work input to refrigerator equals:
      a) Qh − Qc
      b) Qc − Qh
      c) Qh + Qc
      d) Zero

      Correct Answer is option a. Qh − Qc

      Explanation: Work = heat rejected − heat absorbed.


      Topic: Carnot Engine Independence

      91. Carnot efficiency is independent of:
      a) Temperature
      b) Pressure
      c) Working substance
      d) Reservoirs

      Correct Answer is option c. Working substance

      Explanation: Depends only on Th and Tc.


      Topic: Disorder with Temperature

      92. Increasing temperature of a system generally:
      a) Decreases entropy
      b) Increases entropy
      c) No effect
      d) Makes entropy zero

      Correct Answer is option b. Increases entropy

      Explanation: Higher temperature increases molecular randomness.


      Topic: Entropy Law

      93. Entropy of universe:
      a) Always decreases
      b) Always increases
      c) Remains constant
      d) Becomes zero

      Correct Answer is option b. Always increases

      Explanation: Total entropy of universe increases.


      Topic: Thermodynamic Cycle

      94. In a cyclic process, change in internal energy is:
      a) Maximum
      b) Minimum
      c) Zero
      d) Infinite

      Correct Answer is option c. Zero

      Explanation: System returns to initial state.


      Topic: Cyclic Process Work

      95. In cyclic process, net work done equals:
      a) Change in internal energy
      b) Zero
      c) Net heat supplied
      d) Entropy change

      Correct Answer is option c. Net heat supplied

      Explanation: ΔU = 0, so Q = W.


      Topic: Efficiency Comparison

      96. Carnot engine efficiency compared to real engines is:
      a) Lower
      b) Equal
      c) Higher
      d) Zero

      Correct Answer is option c. Higher

      Explanation: Carnot engine is ideal and maximum efficiency.


      Topic: Entropy and Order

      97. A highly ordered system has:
      a) High entropy
      b) Low entropy
      c) Infinite entropy
      d) No entropy

      Correct Answer is option b. Low entropy

      Explanation: Order means less randomness.


      Topic: Thermodynamic Processes

      98. In which process no work is done?
      a) Isothermal
      b) Isobaric
      c) Isochoric
      d) Adiabatic

      Correct Answer is option c. Isochoric

      Explanation: Volume is constant, so W = 0.


      Topic: Heat and Internal Energy

      99. When gas is compressed adiabatically, its internal energy:
      a) Decreases
      b) Increases
      c) Remains constant
      d) Becomes zero

      Correct Answer is option b. Increases

      Explanation: Work done on gas increases internal energy and temperature.


      Topic: Entropy Direction

      100. Direction of spontaneous process is determined by:
      a) Energy
      b) Work
      c) Entropy
      d) Pressure

      Correct Answer is option c. Entropy

      Explanation: Processes occur in direction of increasing entropy.